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GEISA 2003


 


GEISA-03 sub-database on Microphysical and Optical

Properties of Atmospheric Aerosols


List of archived refractive indices of basic atmospheric aerosol components
(complex refraction indices : m=p-iq)



for

SOLID SUBSTANCES
WATER (Droplets)
WATER SOLUBLE COMPONENTS
H2SO4 SOLUTION
HNO3 SOLUTION
WATER ICE
THIN FILMS
TERNARY H2SO4/HNO3/H2O SOLUTION DROPLETS





Solid substances



 

Component

#

p/q

refraction

indices

 

Temperature

(K)

 

p

q

 

References

Wavenumber (cm-1)

min

max

min

max

Ammonium Sulfate (Crystalline form)

61/61

(*)

164

50000 1

164

50000 1

Toon et al., 1976

Ash

61/61

(*)

250

50000

250

50000

Volz F., 1972, 1973; Shettle and Fenn, 1979.

Carbonaceous

61/61

(*)

164

50000

164

50000

Shettle and Fenn, 1979; Twitty, J. T. and Weinman, 1971

Dust-Like

68/68

(*)

33

50000

33

50000

 

Dust-Like

61/61

(*)

250

50000

250

50000

Volz F., 1972, 1973; Shettle and Fenn, 1979.

Hematite

(Iron Oxide)

68/68

(*)

33

50000

33

50000

Longtin et al., 1988; Galuza et al., 1979; Kerker et al., 1979; Steyer, 1974; Onari, 1977

Insoluble

61/61

Room temperature

250

40000

250

40000

Shettle and Fenn, 1979

Meteoric Dust

62/62

Room temperature

200

50000

200 1

50000

Fenn et al., 1985; Shettle, and Volz, 1976

Mineral (nucleus mode)

61/61

Room temperature

250

40000

250

40000 1

Carson and Benjamin, 1980; Sokolik et al., 1993

Mineral (accumulation mode)

61/61

Room temperature

250

40000

250

40000

Carson and Benjamin, 1980; Sokolik et al., 1993

Mineral (coarse mode)

61/61

Room temperature

250

40000

250

40000 1

Carson and Benjamin, 1980; Sokolik et al., 1993

Mineral-transported

61/61

Room temperature

250

40000

250

40000

Carson and Benjamin, 1980; Sokolik et al., 1993

Quartz

68/68

Room temperature

33

50000

33

50000

Gray, 1963; Drummond, 1936; Spitzer, and Kleinman, 1961; Philipp, 1985; Longtin et al., 1988

Sand

68/68

(*)

33

50000

33

50000

Longtin et al., 1988

Sea Salt

(Crystalline form)

90/90

Room temperature

0.33

50000

0.33

50000

Dorsey, 1940; Volz, 1972a;

Shettle and Fenn, 1979;

Sea salt (accumulation mode) (+)

61/61

Room temperature

250

40000

250

40000

Shettle and Fenn, 1979

Sea salt (coarse mode) (+)

61/61

Room temperature

250

40000

-250

40000

Shettle and Fenn, 1979

Sodium Chloride (Crystalline form)

90/90

(*)

0.33 1

50000

0.33

50000

Eldridge and Palik, 1985

Soot

61/61

Room temperature

250

40000

250

40000

Shettle and Fenn, 1979

Volcanic Dust

62/62

Room temperature

200

50000

200

50000

Volz, 1973

(*) Missing value

(+) Refraction indices of aerosol components which are able to take up water are available for eight values of relative humidity: 0%, 50%, 70%, 80%, 90%, 95%, 98%, 99%.




Water (droplets)



 

Components

#

p/q

refraction

indices

 

Temperature

(K)

 

P

q

 

References

Wavenumber (cm-1)

min

max

min

max

Water

0/186

265, 295

(*)

(*)

6940

10640

Kou et al., 1993

Water

0/218

295

(*)

(*)

10660

15000

Kou et al., 1993

Water

420/420

290

10

5000

10

5000

Downing and D. Williams, 1975

Water

90/90

283

0.33

50000

0.33

50000 1

Hale and Querry, 1973; Ray 1972




Water-soluble components



Components

#

p/q

refraction

indices

 

Temperature

(K)

 

p

q

References

Wavenumber (cm-1)

min

max

min

max

Water Soluble

61/61

Room temperature

250

50000

250

50000

Volz F., 1972, 1973; Shettle and Fenn, 1979.




H2SO4 solutions



Components

#

p/q

refraction

indices

[Solution concentration] (%)

Temperature (K)

P

q

References

Wavenumber (cm-1)

min

max

min

max

H2SO4

solution

8192/4768

[57]

183

0

16382

432

5028

Biermann et al., 2000

H2SO4

solution

8192/4768

[57, 64]

188

0

16382

432

5028

Biermann et al., 2000

H2SO4

Solution

8192/4768

[30, 57, 64]

193

0

16382

432

5028

Biermann et al., 2000

H2SO4

Solution

8192/4768

[30, 45, 57, 64]

203

0

16382

432

5028

Biermann et al., 2000

H2SO4

Solution

8192/4768

[30, 45, 57, 60, 64]

213

0

16382

432

5028

Biermann et al., 2000

H2SO4

Solution

8192/4768

[70, 75, 80]

215

0

16382

432

5028

Biermann et al., 2000

H2SO4

Solution

8192/4768

[40, 50, 60]

223

0

16382

432

5028

Biermann et al., 2000

H2SO4

solution

8192/4768

[30, 40, 45, 50, 57, 60, 64]

233

0

16382

432

5028

Biermann et al., 2000

H2SO4

solution

8192/4768

[20, 30, 40, 45, 50, 57, 60]

253

0

16382

432

5028

Biermann et al., 2000

H2SO4

solution

8192/4768

[0, 10]

263

0

16382

432

5028

Biermann et al., 2000

H2SO4

solution

8192/4768

[0, 10, 20, 30, 40, 45, 50, 57, 60, 64]

273

0

16382

432

5028

Biermann et al., 2000

H2SO4

solution

8192/4768

[0, 10, 20, 30, 40, 45, 50, 57, 60, 64, 75, 80]

293

0

16382

432

5028

Biermann et al., 2000

H2SO4

solution

2010/2010

[45, 50]

200

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

2010/2010

[32, 39, 61]

210

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

2010/2010

[38, 43, 50, 55, 66, 72]

220

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

2010/2010

[75]

230

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

2010/2010

[42, 50, 59, 69, 80]

240

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

2010/2010

[42, 47, 55, 72, 76%, 87]

260

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

2010/2010

[50, 63, 70, 76, 85]

280

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

2010/2010

[72, 75, 85]

300

825

4700

825

4700

Niedziela et al. 1999

H2SO4

solution

1685/1685

[45.2, 50, 55.1, 61.6, 65.3, 70.2, 75, 80]

(*)

499

6996

499

6996

Tisdale et al., 1998

H2SO4

solution

62/62

[75]

215, 300

200

50000

200

50000

Hummel et al., 1988

H2SO4 (+)

61/61

[75%]

Room temperature

250

40000

250

40000

Fenn et al., 1985

H2SO4

solution

227/227

[25, 38, 50, 75, 84.5, 95.6]

(*)

400

27800

400

27800

Palmer et al., 1975

H2SO4

Solution

44/44

[68]

(*)

850

1087

850

1087

Remsberg et al., 1974

H2SO4

solution

184/184

[75]

(*)

547

1571

547

1571

Remsberg et al., 1974

H2SO4

solution

211/211

[90]

(*)

748

1567

748

1567

Remsberg et al., 1974

H2SO4

61/61

[75]

(*)

250

50000

250

50000

Volz F., 1972, 1973; Shettle and Fenn, 1979.




HNO3 solutions



Components

#

p/q

refraction

indices

[Solution concentration] (%)

Temperature (K)

p

q

References

Wavenumber (cm-1)

min

max

min

max

HNO3

solution

8192/4768

[40, 45]

213

0

16382

432

5028

Biermann et al., 2000

HNO3

solution

8192/4768

[30, 45, 50]

223

0

16382

432

5028

Biermann et al., 2000

HNO3

solution

8192/4768

[30, 40, 45, 50]

233

0

16382

432

5028

Biermann et al., 2000

HNO3

solution

8192/4768

[30, 40, 45, 50]

253

0

16382

432

5028

Biermann et al., 2000

HNO3

solution

8192/4768

[0, 20]

263

0

16382

432

5028

Biermann et al., 2000

HNO3

solution

8192/4768

[0, 10, 20, 30, 40, 45, 50]

273

0

16382

432

5028

Biermann et al., 2000

HNO3

solution

8192/4768

[0, 10, 20, 30, 40, 45, 50]

293

0

16382

432

5028

Biermann et al., 2000

HNO3

solution

1802/1802

[3.1, 6.1, 11.8, 22.3, 40.3, 70]

(*)

250

4987

250

4987

Querry and Tyler, 1980




water ice



Components

#

p/q

refraction

indices

 

Temperature

(K)

p

q

References

Wavenumber (cm-1)

min

max

min

max

Ice

3318/3318

130, 140 , 150 , 160 , 170 ,180 , 190 , 200 , 210

802

4000

802

4000

Clapp et al., 1995

Ice

0/147

248

(*)

(*)

4000

6920

Kou et al., 1993

Ice

468/468

267

59

22570

59

22570

Warren, 1984

Ice

90/90

(*)

0.33 1

50000

0.33

50000

Fenn et al., 1985; Warren, 1984

Ice

62/62

272, 268 ,253 , 213

0

60

0

60

Warren, 1984




thin films



Components

#

p/q

refraction

indices

 

Temperature

(K)

p

q

References

Wavenumber (cm-1)

min

max

min

max

NAT

589/589

160

711

4004

711 -

4004 -

Richwine et al., 1995

a-NAD film

113/113

153

482

6160

482

6160

Toon et al., 1994

a-NAM film

124/124

153

482

6443

482

6443

Toon et al., 1994

a-NAT film

120/120

153

482

7000

482

7000

Toon et al., 1994

NAM film

135/135

179

482

6002

482

6002

Toon et al., 1994

ALPHA NAT film

112/112

181

482

6989

482

6989

Toon et al., 1994

NAD film

133/133

184

482

6981

482

6981

Toon et al., 1994

Beta NAT film

110/110

196

482 cm-1

6364

482

6364

Toon et al., 1994

Water Ice film

173/173

163

482

6962

482

6962

Toon et al., 1994


NAD- Nitric Acid Dihydrate

NAM- Nitric Acid Monohydrate

NAT- Nitric Acid Trihydrate




ternary H2SO4/HNO3/H2O solution droplets



Components

[Solution concentration] (%) Temperature (K)

p & q

References

Wavelength (μm)

min

max

H2SO4/HNO3/H2O/

solution

[10, 45]

220

2.0001

12.1126

Norman, M.L., R.E. Miller, D.R. Worsnop, 2002

H2SO4/HNO3/H2O/

solution

[22, 35]

220

2.0001

12.1126

Norman, M.L., R.E. Miller, D.R. Worsnop, 2002

H2SO4/HNO3/H2O/

solution

[28, 31]

220

2.0001

12.1126

Norman, M.L., R.E. Miller, D.R. Worsnop, 2002

H2SO4/HNO3/H2O/

solution

[29, 26]

220

2.0001

12.1126

Norman, M.L., R.E. Miller, D.R. Worsnop, 2002

H2SO4/HNO3/H2O/

solution

[33, 24)

220

2.0001

12.1126

Norman, M.L., R.E. Miller, D.R. Worsnop, 2002

H2SO4/HNO3/H2O/

solution

[40, 15]

220

2.0001

12.1126

Norman, M.L., R.E. Miller, D.R. Worsnop, 2002

 

 

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REFERENCES